kovové prášky pro 3d tisk

Kovové prášky are a critical raw material for additive manufacturing using powder bed fusion technology. This guide provides an overview of various metal powders used in 3D printing processes like selective laser melting (SLM) and electron beam melting (EBM).

Introduction to Metal Powders for AM

Metal powders enable printing of complex, high-performance metal parts using additive manufacturing.

Materials used:

• Nerezové oceli
• Nástrojové oceli
• Kobalt-chromové slitiny
• Titan a slitiny titanu
• Slitiny hliníku
• Niklové superslitiny
• Slitiny mědi

Key powder properties:

• Chemistry – Purity and composition
• Tvar a morfologie částic
• Distribuce velikosti částic
• Zdánlivá hustota a hustota odbočky
• Tekutost
• Opětovné použití prášku

Powder production methods:

• Rozprašování plynu
• Rozprašování vody
• Plazmová atomizace
• Indukční tavení elektrod
• Karbonylový proces
• Mechanické legování

Prášky z nerezové oceli

Stainless steel powders are commonly used for printing corrosion resistant parts:

Alloy types:

• Austenitic steels like 316L, 304L
• Martensitic steels like 17-4PH
• Duplex steels like 2205
• Precipitation hardening like 17-4PH, 15-5PH

Charakteristika:

• Vysoká odolnost proti korozi a oxidaci
• Good strength and ductility
• Less prone to cracking than high-alloy steels
• Parameters like build atmosphere critical

Aplikace:

• Chemical and process industry parts
• Marine components
• Lékařské implantáty a přístroje
• Food/pharma industry parts requiring hygiene

Dodavatelé: Carpenter, Sandvik, Praxair, Höganäs, LPW Technology

Prášky z nástrojové oceli

Tool steels like H13 are ideal for printing wear and high-hardness parts:

Alloy types:

• Shock-resistant steels like S7
• Cold work steels like D2
• Hot work steels like H13, H11
• High speed steels like M2

Charakteristika:

• Excellent hardness up to 60 HRC
• Vysoká odolnost proti opotřebení
• Good toughness and thermal fatigue resistance
• Require high-temperature solution annealing

Aplikace:

• Metal forming dies and molds
• Řezné nástroje a vrtáky
• Wear parts and bearings
• High-temperature tooling

Dodavatelé: Sandvik, Erasteel, LPW Technology, Tekna Plasma Systems

Slitiny kobaltu a chromu

Cobalt-chrome powders print biocompatible implants and dental restorations:

Alloy types:

• CoCrMo like Co-28Cr-6Mo
• CoNiCrMo like Co-35Ni-20Cr-10Mo
• CoCr like Co-67Cr-28Fe

Charakteristika:

• Vynikající biokompatibilita a odolnost proti korozi
• Vysoká pevnost a tvrdost
• Wear resistance for articulating joints
• Challenging printability and cracking tendency

Aplikace:

• Dental copings, bridges and crowns
• Orthopedic knee and hip implants
• Fixation devices like cranial plates
• Spinal fusion hardware

Dodavatelé: SLM Solutions, Carpenter, Arcam EBM

Titanové prášky

Titanium powders create strong, lightweight printed parts:

Alloy types:

• Unalloyed titanium like Ti Grade 1-4
• Slitina Ti-6Al-4V
• Ti-6Al-7Nb alloy
• Other alpha + beta alloys

Charakteristika:

• Vysoký poměr pevnosti a hmotnosti
• Vynikající odolnost proti korozi
• Dobré vysokoteplotní vlastnosti
• Low density – 4.5 g/cc
• Reactive and requires inert atmosphere

Aplikace:

• Aerospace and motorsports components
• Lékařské implantáty a protetika
• Food/chemical industry parts
• Automobilové díly

Dodavatelé: AP&C, Tekna, Carpenter Additive

Hliníkové slitiny

Aluminum powders print lightweight structural or functional parts:

Alloy types:

• AlSi 10Mg
• AlSi7Mg
• AlSi12
• Scalmalloy® and other Al alloys

Charakteristika:

• Low density – 2.7 g/cc
• Good strength and stiffness
• Vynikající tepelná vodivost
• Prone to cracking and residual stresses

Aplikace:

• Automotive and motorsports components
• Aerospace and space applications
• Výměníky tepla
• Medical equipment like casts

Dodavatelé: AP&C, Sandvik, LPW Technology, ECKA Granules

Niklové superslitiny

Nickel superalloys like Inconel 718 print high-temperature parts:

Alloy types:

• Inconel 718
• Inconel 625
• Waspaloy
• Hastelloy X

Charakteristika:

• Vynikající pevnost při vysokých teplotách
• Good corrosion and creep resistance
• Ability to work under stress at high temps
• Challenging to process and prone to cracking

Aplikace:

• Lopatky turbíny
• Díly spalovací komory
• Komponenty kosmické lodi
• Nuclear/chemical industry parts

Dodavatelé: Praxair, Carpenter Additive, GE Additive

Slitiny mědi

Copper alloys like CuCrZr print highly conductive parts:

Alloy types:

• Copper-chromium like CuCr1Zr
• Copper-nickel like CuNi2SiCr
• Bronzes like CuSn10

Charakteristika:

• Vynikající tepelná a elektrická vodivost
• Dobrá odolnost proti korozi
• Antibacterial property
• Lower strengths than steels and Ni alloys

Aplikace:

• Electrical components like busbars
• Heat exchangers and heat sinks
• Waveguides and RF components
• Medical instruments and fixations

Dodavatelé: Sandvik, LPW Technology, Metalysis

Technické specifikace

Typical metal powder specifications used in AM:

Parametr	Typické hodnoty	Test Standards
Velikost částic	10 - 45 μm	ASTM B214
Tvar částic	Sférické	ISO 13322-2
Průtoková rychlost	25 - 35 s/50 g	ASTM B213
Zdánlivá hustota	2 - 5 g/cc	ASTM B212
Hustota poklepání	4 – 8 g/cc	ASTM B527
Zbytkový kyslík	< 300 ppm	In-house method
Zbytkový dusík	< 50 ppm	In-house method
Zbytkový uhlík	< 30 ppm	ASTM E1019

Způsoby výroby prášku

1. Atomizace plynu

• Vysoce sférický prášek
• Small particle sizes of 5-100 μm
• Used for reactive alloys like titanium

2. Atomizace vody

• Irregular powder shape
• Larger particles up to 300 μm
• Lower cost process

3. Plazmová atomizace

• Controlled particle shapes
• Submicron to 150 μm sizes
• High purity powder

4. Mechanical Alloying

• Elemental blending and milling
• Cost-effective for custom alloys
• Large particle sizes

Dodavatelé a ceny

Dodavatel	Materiály	Cenové rozpětí
Technologie LPW	Nástrojové oceli, nerezové oceli	$50 - $120/kg
AP&C	Titanium alloys, Al alloys	$70 – $450/kg
Sandvik	Stainless steels, Ni alloys	$45 – $250/kg
Praxair	Superalloys, titanium	$150 – $600/kg
Přísada pro tesaře	Tool steels, CoCr, stainless	$80 - $300/kg

• Stainless steel powders cost $45-$120 per kg
• Titanium alloy powders cost $150-$450 per kg
• Superalloys and tool steels cost $250-$600 per kg

Prices depend on alloy, quality, lot size, and purchase agreements.

Powder Handling and Storage

To prevent contamination, proper powder handling is critical:

• Use dedicated powder sieving areas
• Ensure inert atmosphere gloveboxes and hoppers
• Use conductive containers to dissipate static charges
• Ground all equipment and transport containers
• Avoid contact with oil, water, or oxygen
• Store powder in sealed containers under inert gas
• Control temperature and humidity during storage
• Follow safety precautions like PPE when handling

Proper storage extends powder reuse life.

Powder Sieving

Sieving ensures consistent particle sizes:

Výhody:

• Removes satellite particles that cause defects
• Breaks up agglomerates
• Improves flow and packing density
• Reduces recyclability issues
• Removes foreign contaminants

Procedure:

• Sieve powder using mesh sizes around 20-63 μm
• Sieve using rotational or vibratory sieving
• Perform sieving under inert atmosphere
• Document remaining powder weight percentage

Sieving improves part quality by ensuring ideal powder spreadability.

Installation and Commissioning

Installing a metal AM printer with powder system involves:

• Cleaning equipment surfaces to avoid contamination
• Leak testing inert gas connections
• Checking laser or electron beam power
• Loading and testing powder recoating system
• Integrating chiller, exhaust, and service connections
• Installing monitoring and safety sensors
• Verifying powder sieving and handling systems
• Calibrating build plate levelling
• Test printing sample parts and validating quality

Vendors provide installation and commissioning support.

Operation and Best Practices

Printer operation guidelines:

• Perform regular leak checks and inert gas purity tests
• Precondition powder to ensure consistent texture
• Adjust layer thickness and laser parameters for new materials
• Closely monitor the melt pool and control part temperature
• Validate critical dimensions using test prints
• Monitor powder condition and reuse only within recommendations
• Perform regular maintenance on optics, beam delivery system and powder recoating mechanism

Personnel safety:

• Use appropriate PPE such as respirators and gloves
• Avoid contact with reactive fine metal powders
• Handle waste powder properly under inert atmosphere

Part post-processing:

• Use appropriate solution heat-treatment and ageing temperatures tailored to alloy and application
• Control ramp rates during thermal processing to relieve stresses
• Use hot isostatic pressing for complex parts if needed to improve densities
• Apply finishing steps like CNC machining and polishing

Maintenance and Inspection

Regular maintenance activities:

Daily:

• Inspect optics like mirrors, lenses, windows for damage
• Clean the build chamber and powder handling system
• Check inert gas levels and recharge if needed
• Test the sieve mechanism and powder recoater

Weekly:

• Calibrate sensors and instrumentation
• Check fasteners, electrical terminals and grounding
• Lubricate and inspect moving parts like motors and drives
• Monitor filters for replacement

Monthly:

• Leak test inert gas system using helium
• Inspect safety devices like fire detectors
• Check the CHP system health

Yearly:

• Schedule preventive maintenance with equipment vendor
• Calibrate laser power meter
• Replace filters and consumable items

Maintenance as per vendor guidelines is required to sustain part quality and equipment health.

Choosing the Right Metal Printing System

Factors to consider when selecting a metal AM machine:

1. Production Requirements

• Type of components to be produced
• Material needed based on part properties
• Production volume requirements
• Required accuracy and surface finish

2. Printer Specifications

• Supported materials and parameters
• Build size and speed
• Precision and repeatability
• Inert atmosphere management
• Automation features and controls

3. Powder Handling System

• Integrated or standalone system
• Sieving, feeding, storage and reuse capabilities
• Containment for reactive materials like titanium
• Monitoring features to avoid contamination

4. Standards Compliance

• Industry standards like ASTM F3301
• Manufacturer quality certifications
• Safety standards compliance

5. Supplier Credentials

• Proven track record in AM industry
• Local sales and technical support capabilities
• Maintenance contracts and services offered
• Operator training plans
• Overall cost of ownership

Thorough requirements analysis and comparisons of machine offerings using these criteria results in the selection of the ideal 3D metal printing system tailored to the production needs.

Pros and Cons of Metal AM

výhody:

• High geometric complexity printed easily
• Shorter time to functional parts
• Reduced waste compared to subtractive processes
• Single setup production directly from CAD
• Lightweighting and part consolidation potential
• Performance improvements with engineered alloys
• Customization and mass customization capabilities

Nevýhody:

• Vysoké náklady na stroje a materiál
• Additional post-processing steps required
• Limited size based on build chamber
• Control of internal defects can be challenging
• Material properties can vary versus wrought
• Surface finish limitations may require finishing
• Training and expertise requirements

Troubleshooting Common Metal AM Issues

Defekt	Možné příčiny	Nápravná opatření
Pórovitost	Improper process parameters	Optimize laser power, speed, hatch spacing
	Powder contamination	Use fresh sieved powder, improve powder handling
	Insufficient overlap between scan tracks	Adjust beam focus size and overlap
Cracking	Excessive thermal stresses	Optimize preheating, control cooling rate with heaters
	Material prone to cracking	Change orientation to reduce stresses
	Contamination from build atmosphere	Ensure high purity inert atmosphere
Deformace	Nerovnoměrné vytápění nebo chlazení	Optimize scan patterns and restrain part on build plate
Poor Surface Finish	Part temperature too low	Increase preheat temperature
	Improper melt pool fluidity	Adjust power and other parameters
	Contaminated powder	Use fresh powder and improve handling

Nejčastější dotazy

Q: What metal alloy powders can be used for AM?

A: Stainless steels, tool steels, titanium alloys, nickel superalloys, aluminum alloys, cobalt-chrome, and copper alloys are common.

Q: What is the typical range of powder particle sizes used?

A: For PBF-LB/M processes, 10-45 microns is common, with tighter distribution around 20-45 μm.

Q: How long can metal powders last?

A: With ideal argon storage, many alloys last 1-2 years. Reuse life is shorter – 20-100 prints based on alloy.

Q: What post-processing steps are required on metal AM parts?

A: Support removal, heat treatment, surface finishing like CNC machining, polishing and coating are often required.

Q: How are reactive metal powders like titanium and aluminum handled?

A: Specialized powder handling under inert argon atmosphere is needed to prevent oxygen pickup.

Q: What are common powder contamination risks?

A: Exposure to atmosphere leading to oxygen or nitrogen pickup. Metallic particles from machining or wear. Oil and moisture.

Q: What standards are used for qualifying metal powders?

A: ASTM B214, ASTM B812, ASTM F3049, ASTM F3301, and MPIF standards.

Q: Why is powder sieving important?

A: It breaks up agglomerates, removes satellites, and provides optimum and consistent powder size for high density and surface finish.

Závěr

Metal powders enable additive manufacturing of advanced, high-performance components with properties better than wrought materials in some cases. A wide range of alloys from stainless steels to superalloys and titanium are available in powder form, tailored to demanding applications across aerospace, medical, automotive, and general industries. With continual improvements in alloys, quality standards, production processes, machinery, and part properties – metal AM is maturing into a core production technology globally. However, process and material expertise and rigorous quality control are essential to realize the full benefits. As more experience is gained, metal AM provides unprecedented capabilities to manufacture complex and customized parts with greater design freedom and shorter lead times.

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