Prášek Ti6Al4V
Obsah
Přehled
Prášek Ti6Al4V, also known as Ti-6Al-4V, Grade 5 titanium, Ti 6-4 or Ti 6/4, is a titanium alloy powder consisting of titanium, 6% aluminum and 4% vanadium. It offers an exceptional combination of high strength, low weight, corrosion resistance and biocompatibility which makes it an extremely versatile material for advanced applications in aerospace, medical devices, marine hardware and more.
Ti6Al4V is considered the workhorse of titanium alloys, accounting for over 50% of total titanium usage the world over. It has among the best strength-to-weight ratios of any metallic material and maintains its properties at extreme temperatures.
Some key properties and characteristics of Ti6Al4V powder include:
- Excellent strength-to-weight ratio, high specific strength
- Low density – 4.43 g/cm3
- Vysoká odolnost proti korozi
- Biocompatibility and osseointegration ability
- Good high temperature properties – usable up to 400°C with oxidation resistance up to 550°C
- Vysoká lomová houževnatost a únavová pevnost
- Available in different size ranges and morphologies – spherical, angular
With its versatile properties, Ti6Al4V finds diverse applications across industries today.
Ti6Al4V Powder Types
Ti6Al4V alloy powder is available in different size distributions, shapes and production methods to suit specific applications:
Typ | Charakteristika |
---|---|
Gas atomized spherical | – Near spherical morphology, smooth surface – Tight particle size control – Used in AM, MIM, thermal spray |
Plasma atomized spherical | – Highly spherical with smooth surface – Narrow size distribution – Used in AM processes |
Hydrid-dehydrid (HDH) | – Irregular, angular morphology – Porous, spongy particles – Lower production cost – Used in MIM, pressing, thermal spray |
Velikost částic: Available from 15 microns to 150+ microns depending on production method
Rozložení velikosti: Graded/sieved, blended or custom specifications
standardy: ASTM B348, AMS 4943, AMS 4928, AMS 4967
Složení prášku Ti6Al4V
Ti6Al4V conforms to Aerospace Material Specification (AMS) 4928 and has the nominal composition:
Živel | Rozsah složení |
---|---|
Titan | Balance, 87.725 – 91% |
Hliník | 5.5 – 6.76% |
Vanad | 3.5 – 4.5% |
Žehlička | Max 0.30% |
Kyslík | Max 0.20% |
Dusík | Max 0.05% |
Uhlík | Max. 0,08% |
Vodík | Max 0.015% |
Iron, oxygen and nitrogen are commonly found impurity elements. The composition is routinely analyzed to ensure it meets aerospace grade specifications before atomization into powder.
Ti6Al4V Powder Properties
Ti6Al4V is prized for its exceptional balance of mechanical properties, corrosion resistance, lightness and biocompatibility. Its properties include:
Physical & Mechanical Properties | Hodnoty |
---|---|
Hustota | 4,43 g/cm3 |
Bod tání | 1604 – 1660°C |
Maximální pevnost v tahu | 860 - 965 MPa |
Mez kluzu (posun 0,2%) | 795 – 875 MPa |
Modul pružnosti | 114 GPa |
Prodloužení po přetržení | 10 – 18% |
Tvrdost | 334 – 361 HV |
Fatigue Strength (107 cycles) | 400 – 490 MPa |
Lomová houževnatost | 55 – 115 MPa-m^0.5 |
Tepelné vlastnosti
Coefficient of Thermal Expansion – 8.6 x 10-6 /K (20-100°C)
Thermal Conductivity – 7.2 W/m.K
Maximum Service Temperature – 400°C
Odolnost proti korozi
Excellent corrosion resistance comparable to unalloyed titanium Resists corrosion by most acids, moist gases, organic chemicals
Formation of stable and highly adhesive oxide surface layer gives it excellent resistance to saline environments. Ti6Al4V demonstrates protection superior to stainless steel in chloride solutions due to lower oxygen and chloride diffusion rates.
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Aplikace prášku Ti6Al4V
Thanks to its well-balanced properties, Ti6Al4V finds diverse industrial and medical applications today:
Průmysl | Aplikace |
---|---|
Aerospace | – Aircraft structural components like wings, landing gear, turbines, fasteners – Rocket motor casings, space vehicles – Helicopter rotor hub, compressor blades |
Lékařské a zubní služby | – Orthopedic implants – hip, knee joints – Dental implants, fixtures, crowns – Maxillofacial implants – Surgical instruments |
Automobilový průmysl | – Connecting rods, drive shafts, springs – Racing car parts like valves, pistons – Exhaust components |
Chemické | – Heat exchangers, tanks, pipes carrying corrosive media – Valves, condensers, distillation columns – Pumps and housings |
Power & Energy | – Steam and gas turbine components – Structural parts for reactors – Renewables -high performance offshore |
Námořní | – Propellers, connecting rods – Corrosion resistant fasteners, hinges – Desalination equipment |
Additive manufacturing is expanding the applications for titanium alloys in all these sectors by enabling freeform geometries not possible previously.
Specifikace prášku Ti6Al4V
Standard | Popis |
---|---|
ASTM B348 | Standard specification for titanium and titanium alloy bars and billets |
AMS 4928 | Aerospace material specification for titanium alloy sheet, strip and plate 6Al – 4V annealed |
AMS 4943 | Chemical check analysis limits for titanium and titanium alloys |
AMS 4967 | Aerospace material specification for powder, titanium alloy 6Al-4V |
ISO 21388 | Specification for unalloyed titanium for surgical implant applications |
ASME SB-348 | Specifikace tyčí a předvalků z titanu a slitin titanu |
Titanium grade 5 Eli powder also needs to meet additional customer requirements pertaining to:
- Tvar částic
- Tekutost
- Zdánlivá hustota
- Hustota poklepání
- Pycnometer density
- Chemická analýza
- Mechanické vlastnosti
Manufacturers producing Ti6Al4V powder follow certified quality management systems and testing protocols before supplying to customers across defense, aerospace, energy, motorsports and medical sectors among others.
Dodavatelé Ti6Al4V prášku
Ti6Al4V powder is manufactured via gas atomization or plasma atomization to produce spherical powder suitable for AM. The starting raw material is vacuum arc remelted (VAR) or electron beam melted (EBM) alloy slab which is atomized into fine droplets that solidify into powder particles on rapid cooling.
Key global suppliers of Ti6Al4V spherical and pre-alloyed powders are:
Společnost | Země |
---|---|
AP&C | Kanada |
Práškové kovy ATI | USA |
TLS Technik GmbH | Německo |
GKN Hoeganaes | USA |
Pokročilé materiály Tekna | USA |
Slm Solutions | Německo |
Erasteel | Francie |
Ti6Al4V powder can be procured in small quantities for research and prototyping applications. Custom alloys and particle characteristics are also possible for companies with established supply agreements.
Cena:
As a high performance alloy requiring advanced manufacturing, Ti6Al4V powder commands a premium over standard grades of titanium and other metal powders. Pricing varies from $100/kg to $500/kg based on:
- Objednané množství
- Tvar částic a rozdělení podle velikosti
- Customization of chemistry/mechanical properties
- Testing and certification requirements
- Economic factors – supply-demand dynamics, raw material costs
Higher purity grades used in medical devices and aerospace applications are costlier. Costs have seen a declining trend with ramp up in production capacities globally.
How to Choose Ti6Al4V Powder
Selection of appropriate Ti6Al4V powder depends upon your specific application and process requirements. Some key considerations include:
Aditivní výroba
- Particle shape – spherical/shaped distributions for better flow and packing
- Particle size – fine <45 microns for better resolution and surface finish
- Narrow size range – ensures uniform melting and densification
- High powder purity >99.5% titanium for lower contamination
- Low oxygen, nitrogen and carbon content
Vstřikování kovů (MIM)
- Irregular, angular powder for higher green strength
- Medium particle size – 100 mesh
- Powder blend with binder components
- Economic grade meeting cost targets
Tepelný nástřik
- Particle size suitable for spray process
- Porous HDH hydride powder allows better coating bonding
- Možnost vývoje slitin na zakázku
Prášková metalurgie
- Angular, porous powder for compaction
- Powder blend tailored to application
- Alloy modified for sintering response
Do consult powder producers early in the design process to select the optimum powder suited for your specific component requirements.
Advantages and Limitations of Ti6Al4V Powder
Výhody
- Vysoký poměr pevnosti a hmotnosti
- Zachovává si vlastnosti při zvýšených teplotách
- Vynikající odolnost proti korozi
- Bioinert – does not produce adverse reactions when implanted
- Powder feedstock allows complex, net-shape part fabrication via AM
- Tailorable mechanical properties by heat treatment
- Recyclable to minimize wastage
Omezení
- High material cost compared to steels and aluminum alloys
- Requires high processing temperatures oxygen contamination risk
- Lower stiffness than steel
- Sharp notch sensitivity – cracking risk
- Difficult to machine requiring special tooling
Engineers select Ti6Al4V where strength, temperature resistance, biocompatibility and corrosion resistance needs outweigh cost constraints in critical structural parts.
Ti6Al4V Powder vs. Alternatives
Ti6Al4V competes against stainless steels, cobalt chromium alloys, aluminum grades and pure titanium. Comparison on key parameters is highlighted below:
Ti6Al4V | Nerezová ocel 316L | Slitina CoCrMo | Al 6061 | Pure Ti Grade 2 | |
---|---|---|---|---|---|
Mez kluzu | 860 MPa | 290 MPa | 655 MPa | 55 MPa | 370 MPa |
Hustota | 4,43 g/cc | 8 g/cm3 | 8,3 g/cc | 2,7 g/cc | 4.51 g/cc |
Youngův modul | 114 GPa | 193 GPa | 230 GPa | 69 GPa | 105 GPa |
Tepelná vodivost | 7 W/mK | 12 W/mK | 9 W/mK | 180 W/mK | 7 W/mK |
Bod tání | 1640°C | 1375°C | 1350°C | 650°C | 1668°C |
Odolnost proti korozi | Vynikající | Dobrý | Veletrh | Dobrý | Vynikající |
Srovnání nákladů | 10x vs Al, 4x vs Steel | Lower cost base | 2x cost vs steel | Lowest cost | 8x cost vs Ti grade 2 |
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