Hoe het gasverstuivingsproces werkt

Overzicht

Gas atomization is a metal powder production method that uses high-velocity inert gas jets to disintegrate a molten metal stream into fine spherical powder particles. The gas atomization process achieves excellent control over powder particle size distribution, morphology, purity, and microstructure.

Key attributes of gas-atomized powder include spherical particle shape, high purity, fine sizes down to 10 microns, and uniform composition. Gas atomization facilitates advanced powder-based manufacturing techniques like metal injection molding, additive manufacturing, and powder metallurgy pressing and sintering.

This guide provides a comprehensive overview of the gas atomization process and powder. It covers atomization methods, particle formation, process parameters, equipment, applicable alloys, powder characteristics, product specifications, applications, and suppliers. Helpful comparison tables are included to summarize technical details.

Hoe de Verstuiving van gas Werken

Gas atomization converts molten alloy into powder using the following fundamental steps:

Gas Atomization Process Stages

• Smeltend – Alloy is melted in an induction furnace and superheated above its liquidus temperature
• Gieten – Molten metal stream poured into an atomization chamber
• Verneveling – High velocity inert gas jets disintegrate the metal into fine droplets
• Verharding – Metal droplets rapidly solidify into powder particles as they fall through the chamber
• Collectie – Powder particles collected in a cyclone separator at bottom of tower

The key phenomenon occurs when the kinetic energy of the gas jets overcomes the metal’s surface tension to shear the liquid stream into droplets. These droplets freeze into powder particles with spherical morphology.

Careful process control allows tailored powder particle sizes, purity, and microstructures.

Methods of Gas Atomization

There are two primary methods of gas atomization used in industry:

Gas Atomization Methods

Methode	Beschrijving	Voordelen	Beperkingen
Close-coupled atomization	Nozzle in close proximity to melt pour point	Compact design, lower gas use	Potential melt contamination from nozzle
Free-fall atomization	Nozzle located below pour point	Reduced melt contamination	Requires taller atomization tower

Close-coupled designs recycle the atomizing gas but risk some melt oxidation. Free-fall offers cleaner atmosphere with less risk of nozzle reaction.

Additional variants include multiple gas nozzles, ultrasonic atomization, centrifugal atomization, and coaxial nozzle designs for specialized applications.

Gas Atomization Nozzle Designs

Various nozzle designs create the high velocity gas jets needed for atomization:

Gas Atomization Nozzle Types

Nozzle	Beschrijving	Gas Flow Pattern	Druppelgrootte
De Laval	Converging-diverging nozzle	Supersonic	Large, wide distribution
Conical	Simple conical orifice	Sonic	Medium
Slit	Elongated slit orifice	Sonic	Klein
Meervoudig	Array of micro-nozzles	Sonic/supersonic	Very small, narrow distribution

De Laval nozzles use gas acceleration to supersonic velocities but have complex geometry. Sonic nozzles with simplified shapes offer more flexibility.

Smaller droplets and tightly controlled size distribution are achieved by using multiple micro-nozzles or slit configurations.

Powder Formation and Solidification

The shearing of molten metal into droplets and subsequent solidification follow distinct mechanisms:

Powder Formation Stages

• Breakup – Rayleigh jet instability causes perturbations and droplet formation
• Vervorming – Droplets elongate into ligaments due to air drag forces
• Rupture – Ligaments breakdown into droplets close to final size
• Verharding – Rapid cooling via gas contact and radiation forms solid particles
• Deceleration – Loss of velocity as particles move down through atomization chamber

The combined effects of surface tension, turbulence, and air drag determine final particle sizes and morphology. Maximum particle cooling rates over 1,000,000 °C/s quench metastable phases.

Procesparameters

Key gas atomization process parameters include:

Verstuiving van gas Parameters

Parameter	Typisch bereik	Effect on Powder
Gas druk	2-10 MPa	Increasing pressure reduces particle size
Gas velocity	300-1200 m/s	Higher velocity produces finer particles
Gasstroomsnelheid	0.5-4 m3/min	Increases flow for higher throughput and finer sizes
Melt superheat	150-400°C	Higher superheat reduces satellites and improves powder flow
Melt pour rate	10-150 kg/min	Lower pour rates improve particle size distribution
Melt stream diameter	3-8 mm	Larger stream allows higher throughput
Separation distance	0.3-1 m	Greater distance reduces satellite content

Balancing these parameters allows control of powder particle size, shape, production rate, and other characteristics.

Alloy Systems for Gas Atomization

Gas atomization can process almost any alloy into powder form including:

Alloys Suitable for Gas Atomization

• Titanium legeringen
• Nikkel-superlegeringen
• Kobalt superlegeringen
• Roestvrij staal
• Gereedschapsstaal
• Laaggelegeerd staal
• Iron and nickel base alloys
• Edelmetalen
• Intermetallics

Gas atomization requires melting temperatures below the decomposition point of the atomizing gas. Typical gases include argon, nitrogen, and helium.

Refractory alloys with very high melting points like tungsten can be challenging to atomize and often require specialized processing.

Most alloys require melt superheating well above the liquidus temperature to maintain sufficient fluidity for atomization into finely dispersed droplets.

Characteristics of Gas Atomized Powder

Typical characteristics of gas atomized powder:

Gas Atomized Powder Characteristics

Kenmerkend	Beschrijving	Betekenis
Deeltjesmorfologie	Zeer bolvormig	Excellent flowability, packing density
Deeltjesgrootteverdeling	Adjustable in 10-150 μm range	Controls pressed density and sintering behavior
Particle size span	Can achieve tight distributions	Provides uniform component properties
Chemical purity	Typically >99.5% excluding planned alloys	Avoid contamination from nozzle reactions
Zuurstofgehalte	<1000 ppm	Critical for high performance alloys
Schijnbare dichtheid	Up to 60% of theoretical	Indicative of pressibility and handling
Interne porositeit	Heel laag	Good for microstructural homogeneity
Oppervlaktemorfologie	Smooth with some satellites	Indicates process stability

The spherical shape and adjustable size distribution facilitate usage in secondary powder consolidation processes. Tight control over oxygen and chemistry enables high performance alloys.

Specifications for Gas Atomized Powders

International standard specifications help define:

• Deeltjesgrootteverdeling
• Apparent density ranges
• Hall flow rates
• Acceptable oxygen and nitrogen levels
• Allowable microstructure and porosity
• Grenzen aan de chemische samenstelling
• Bemonsteringsprocedures

This supports quality control and reproducible powder behavior.

Specifications for Gas Atomized Powders

Standaard	Materialen	Parameters	Testmethoden
ASTM B964	Titanium legeringen	Particle size, chemistry, microstructure	X-ray diffraction, microscopy
AMS 4992	Aerospace titanium alloys	Particle size, oxygen content	Sieve analysis, inert gas fusion
ASTM B823	Tool steel powder	Schijnbare dichtheid, stroomsnelheid	Hall-stroommeter, Scott-volumemeter
SAE AMS 5050	Nikkel legeringen	Particle size, morphology	Laser diffraction, SEM
MPIF 04	Many standard alloys	Schijnbare dichtheid, stroomsnelheid	Hall-debietmeter, getapte dichtheid

Specifications are tailored to critical application requirements in aerospace, automotive, medical, and other quality-driven industries.

Applications of Gas Atomized Powder

Gas atomized powders enable manufacturing of high performance components via:

• Metaalspuitgieten (MIM)
• Additieve Productie (AM)
• Heet isostatisch persen (HIP)
• Poeder smeden
• Thermal and Cold Spray
• Powder Metallurgy Pressing and Sintering

Benefits versus wrought materials:

• Complex geometries with fine features
• Uitstekende mechanische eigenschappen
• Near full density consolidation
• Novel and customized alloys
• Diverse materiaalopties

Gas atomization excels at producing spherical, flowing powders optimal for automated processing of intricate components with high quality standards across industries.

Global Suppliers of Gas Atomized Powders

Prominent global suppliers of gas atomized powders include:

Gas Atomized Powder Manufacturers

Bedrijf	Materialen	Mogelijkheden
ATI-poedermetalen	Titaan, nikkel, gereedschapsstaallegeringen	Broad alloy range, high volumes
Praxair Oppervlaktetechnologieën	Titanium-, nikkel-, kobaltlegeringen	Wide alloy selection, toll processing
Sandvik Visarend	Stainless steels, low alloy steels	Specialists in ferrous materials
Hogenäs	Gereedschapsstaal, roestvrij staal	Custom alloys, additive manufacturing powders
Timmerman additief	Titanium-, nikkel-, kobaltlegeringen	Custom alloys, specialized particle sizes

Smaller regional suppliers also offer gas atomized powders, often servicing niche alloys or applications.

Many providers also undertake sieving, blending, coating, and other powder post-processing operations.

Advantages vs. Limitations of Gas Atomization

Gas Atomization – Pros and Cons

Voordelen	Beperkingen
Sferische poedermorfologie	Higher upfront capital costs
Controlled particle size distributions	Requires high purity inert gas
Applicable to many alloy systems	Refractory alloys challenging to atomize
Clean powder chemistry and microstructure	Can experience nozzle erosion
Rapid powder quenching preserves metastable phases	Requires melt superheating well above liquidus
Continuous powder production process	Powder shape limits green strength

The spherical shape and fine sizes of gas atomized powder provide distinct advantages but come at a higher operational cost versus simpler mechanical comminution processes.

Selecting Gas Atomized Powder

Key aspects when selecting gas atomized powder:

• Desired chemistry and alloy composition
• Doelverdeling van de deeltjesgrootte
• Suitable apparent and tap density ranges
• Oxygen and nitrogen limits dictated by application
• Flow characteristics for automated powder handling
• Sampling procedures to ensure representativeness
• Vendor technical expertise and customer service
• Total cost considerations

Testing prototype builds helps qualify new alloys and gas atomized powders for an application. Collaborating closely with the powder producer enables optimization.

FAQ

What is the smallest particle size that gas atomization can produce?

Specialized nozzles can produce single-digit micron powder down to 1-5 microns. However, ultrafine powder has very low apparent density and exhibits strong interparticle Van der Waals forces, requiring careful handling.

What causes powder satellites during gas atomization?

Satellites form when droplets are too large or collide and partially rejoin before fully solidifying. Higher superheat, lower pour rates, and increased separation distance all help reduce satellites.

Why is high purity inert gas required for gas atomization?

High velocity gas jets can erode metal from the nozzle over time and contaminate powder. Reactive gases like nitrogen and oxygen also negatively affect powder purity and alloy performance.

Hoe is gasverstuiving te vergelijken met waterverstuiving?

Water atomization produces more irregular powder at larger sizes of 50-150 microns typically. Gas atomization allows finer sizes down to 10 microns with spherical morphologies preferred for pressing and sintering applications.

Wat is centrifugale verstuiving?

In centrifugal atomization, molten metal is poured into a spinning disk that throws off fine molten metal droplets that solidify into powder. This method offers higher production rates than gas atomization but reduced powder size and shape control.

Can you switch alloys quickly during gas atomization?

Yes, with specialized equipment the melt stream can be changed rapidly to produce composite and alloyed powders. However, cross-contamination between alloys should be minimized through chamber purging.

Conclusie

The gas atomization process produces spherical, flowing metallic powders with tightly controlled particle size distribution, purity, and microstructural characteristics optimal for advanced powder consolidation processes across critical applications. Careful manipulation of process parameters and specialized nozzle designs allow extensive control over final powder characteristics. With continued development, gas atomization provides engineers greater ability to manufacture high-performance components in creative new ways.

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